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Download B Boron Compounds: Boron and Noble Gases, Hydrogen by Lawrence Barton, Thomas Onak, Jürgen Faust, Kurt Niedenzu, PDF

By Lawrence Barton, Thomas Onak, Jürgen Faust, Kurt Niedenzu, R. Bohrer

ISBN-10: 3662061449

ISBN-13: 9783662061442

ISBN-10: 3662061465

ISBN-13: 9783662061466

A huge assurance of boron themes is supplied. Structural elucidations and handy routes to beneficial hydroboration reagents are awarded in addition to boron compounds used for clinical reasons. distinct consciousness is dedicated to theoretical reviews and calculations on small boron-hydrogen and boron-noble gasoline species together with molecules like BH, that are particularly favourite topics of theoreticians for trying out quite a few equipment of calculation.

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Extra info for B Boron Compounds: Boron and Noble Gases, Hydrogen

Example text

Workman, D. ; Share, S. G. (Organometallics 6 [1987] 1984/5). 5 Substituted Boranes, RBH 2 and R2 BH Very convenient routes to RBH 2 and R2 BH, both useful as hydroboration reagents, are now available [1 to 3]. The corresponding substituted tetrahydroborates are effectively considered as stabilized forms of these boranes. Treatment of the Li[H 2 BR 2 ] or Li[H 3 BR] species with either HCl, (CH 3 lJSiCl, or (CH 3 lJSi0 3 SCH 3 in diethyl ether or n-pentane affords the corresponding alkylborane.

J. Am. Chem. Soc. 110 [1988] 4208/12). Lipscomb, W. N. (AlP Conf. Proc. No. A. 106 [1986] No. 30324). Ip, W. ; Li, W. K. (Croat. Chem. A. 103 [1984] No. 93609). McKee, M. ; Lipscomb, W. N. (lnorg. Chem. 24 [1985] 762/3). Curtiss, L. ; Pople, J. A. (J. Chem. Phys. 89 [1988] 614/5). ; Mayhew, C. ; Berkowitz, J. (J. Chem. Phys. 88 [1988] 5580/93). Curtiss, L. ; Pople, J. A. (J. Phys. Chem. 92 [1988] 894/9). Cullen, J. ; Lipscomb, W. ; Zerner, M. C. (Chem. Phys. Letters 125 [1986] 313/8). Chesnut, D.

S 38"1tSH 1e--1tBH 1 0 a ' - oss 98'--ttsH ! w 2a"--1tSH 1b1--n8 2a1--1ts 1bz------ttsH 2a~H -20 BHs (Dshl BH 3 ·H 2S H~ Fig. 2-5. Molecular orbital diagram for BH 3 -SH 2 indicating the electronic transitions [3]. BH 3 -S(CH 3 ) 2 may be carbonylated with CO to form trimethylboroxine in 81% yield. 6 mal CO over a period of 12 hours. This reaction is in accord with the following equation: 3 BH 3-S(CH 3)2 + 3 CO-+ [ -0-B(CH 3)-0-B(CH 3)-0-]BCH3 +3 S(CH 3h [20]. 3: [1] Forcada, M. ; San-Fabian, E.

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B Boron Compounds: Boron and Noble Gases, Hydrogen by Lawrence Barton, Thomas Onak, Jürgen Faust, Kurt Niedenzu, R. Bohrer


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